A Photoluminescent Polymeric 2D Silver(I) Complex Exhibits a Fishbone-like 1D Silver Cluster and New Coordination Mode of the Pyridine-2,3-Dicarboxylate
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Erişim
info:eu-repo/semantics/closedAccessTarih
2013Yazar
Çolak, Alper TolgaPamuk, Gönül
Uzun, Nazlı
Yeşilel, Okan Zafer
Semerci, Fatih
Günay, Handan
Büyükgüngör, Orhan
Üst veri
Tüm öğe kaydını gösterÖzet
In this study, a novel organic-inorganic hybrid compound with AgNO3 and 2,3-pyridinedicarboxylic acid (H(2)pydc), [Ag-2(mu(6)-pydc)](n) (1) has been synthesized. The molecular structure of complex has been determined by the single crystal X-ray diffraction. The complex has been observed to crystallize in the monoclinic space group P2(1)/c. The asymmetric unit of compound consists of two crystallographically different Ag(I) centers and one pydc ligand. The Ag1 and Ag2 adopt tetrahedral and T-shaped geometries, respectively. At the same time, the silver(I) compound consists of a fish bone similar to the 1D silver cluster. Furthermore, novel coordination mode shown by H(2)pydc indicates that the crystal exhibits photoluminescence in the solid state at room temperature.
Kaynak
Journal of Inorganic and Organometallic Polymers and MaterialsCilt
23Sayı
2Koleksiyonlar
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